@User
AD connect is always one way sync for objects (users, groups, contacts and devices). AD connect syncs objects from on-prem to Azure AD.
AD connect doesn't writeback user from Azure AD to on-premises AD. The user writeback preview feature was removed in the August 2015 update to Azure AD Connect.
This is also documented in our public document https://learn.microsoft.com/en-us/azure/active-directory/hybrid/how-to-connect-preview#user-writeback
Currently we do not have this feature. However, this might be one of our upcoming features in AD connect.
About your question you had regarding users created directly in Entra ID, you will have to create similar users in on-premises with same UPN and Proxy address.
Once users are created in on-premises AD, you can trigger sync and this will do a soft match for account in on-premises and Entra ID.
Let us know if you have any further questions.
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